Answer
Recommendations apply to ash or other combustion products from combustion:
- household, industrial or commercial waste;
- sewage sediments or other newly generated waste;
- wood and wooden waste;
- rice bran;
- agricultural waste;
- sludge from the gas scrubbing unit;
- any combination of the above.
Ash disposal. The waste to be treated in the unit may contain refractory, non-combustible substances that pass into ash. Their presence affects the ash content: volume and quantitative chemical analysis. Thus, the amount of ash residue can be 3-50%, depending on the loaded waste composition. The output control serves to determine the physical and chemical properties and hazard class of the decontaminated material.
As SMR ashes and residues from waste incineration HS code 2621100000
After thermal waste decontamination of (incineration), secondary waste is generated according to the FCCW:
- 6 11 910 01 49 4 ash from burning sunflower husks;
- 6 11 910 02 49 5 ash from the burning of rice husks;
- 7 42 211 11 49 4 ash from the burning of bark and wood waste and sewage treatment sludge from pulp and paper production;
- 7 46 311 11 40 4 ash from the burning of dewatered sludge of domestic and mixed sewage is low-hazard;
- 7 47 112 11 40 4 ash from the burning of consumer waste in production, similar to municipal waste;
- 7 47 119 11 40 4 ash from the burning of consumption waste in the production, similar to municipal waste, mixed with industrial waste, including oily waste;
- 7 47 813 01 40 4 ash from the burning biological waste from the vivarium and laboratory animal waste;
- 7 47 821 01 40 4 ash from combustion of biological waste from animal housing, slaughter and processing;
- 7 47 841 11 49 4 ash from medical waste incineration, containing mainly silicon and calcium oxides;
- 7 47 911 11 40 4 ash from the combustion of waste paper, cardboard, wood and wood products, containing mainly calcium and magnesium oxides;
- 7 47 911 12 40 4 ash from burning cotton dust, waste paper, cardboard, and wood
- 7 47 931 01 40 4 ash from burning paper, cardboard, wooden containers (packaging) from explosives, pesticides, agrochemicals and other chemical products;
The resulting scale (ash) after processing can form a secondary raw material. The resulting secondary raw materials can be used as a mineral additive or filler in the manufacture of heavy, light, cellular concrete, dry building mixtures, as well as mineral binders for the preparation of mixtures and reinforced soils in road construction. The final consumption of SMR will be: production of foam and gas blocks, ash bricks, paving stones, production of cements and dry building mixes of concrete and piece reinforced concrete products, drainage devices, tiles, production of waterproofing and soundproofing materials, mineral fiber, various composite materials, mastics, sealants, and paint and varnish products, act as a filler in road construction, runways, taxiways, parking lots in airports, in the construction of port facilities, to increase the seismic resistance of buildings and structures, reclamation of quarries, in the construction of landfills, landfill bunding, dumping in garbage dumps, tailings, sludge reservoirs, dams, industrial pools and channels; filling of mined out spaces with ash. (Appendix 2).
If the obtained ash is used for decontamination of the waste containing toxic and ecologically dangerous substances, pelletizing technology is applicable: mixing of 40-60 wt.% of ash, 10-20 wt.% of silicon oxide component of SiO2 — 50-75%, Al2O3
— 530%, Na2O — 5-20%, CaO — 1-10%, 20-40 wt.% of acid component. From the obtained mixture, granules are formed, powdered with dispersed refractory material, dried and heat-treated in two stages: for 10-30 min at 400-600 °С and for 1-20 min at 870-950°С. Technical result: increasing the strength, water resistance of the obtained non-toxic pellets of non-toxic form, and the suitability for safe burial or application. Such a method has been patented as a method of producing ash-filled polymer concretes when high-molecular-weight compounds, such as unsaturated polyester resin, are used as a binder. Such polymer concrete is characterized by high strength characteristics, resistance to chipping, products from it have a pore-free surface.
One way to process ash with a specific surface of 2000-4000 cm2/g, containing salts of heavy metals — cadmium, copper, lead and zinc, mixed with sulfur in a ratio of 1:1-1:2.5 and heated to mastic consistency, after which the mastic is poured into molds for making blocks, or fed to the machine for pelletizing. When testing the samples, in aqueous extracts, zinc, cadmium, copper was not detected, lead — 0.024 mg/l, the content of petroleum products did not exceed 0.1 mg/l, hydrogen sulfide is not released.
Acid ash should be used to partially or completely replace porous sands and reduce the average density of concrete. For structures of underwater and internal zones of hydraulic structures type IV acid ash should be used.
In general, the disposal of ash in the composition provides recycling into environmentally safe products up to 90% of the original mass of ash.
The use of ash as a reclamation agent for mine and quarry workings during mining for the purposes of environmental protection and sanitary and hygienic direction of their reclamation according to GOST 17.5.3.04-83.
At low pH values (less than 5) liming with calcium-containing reagents is used: calcium oxide CaO, calcium oxide Ca(OH)2, and limestone flour (dolomite). At high pH values of initial raw materials (more than 8.5), deoxidation with Phosphogypsum is used. Sorbents and structurizers (pore-forming additives) are used to increase porosity and improve the structure of techno-soil.
The possibility of obtaining amorphous silicon dioxide (ASD) makes it possible to use the inorganic potential of rice husk as a raw material: SiO2 — 80 %, carbon C — 9 %, oxides (Fe2O3 - 0.01 %, Al2O3 — 0.15 %, TiO2 — 0.01 %, MgO - 0.4 %, CaO - 0.98 %, K2O — 2.09 %, Na2O — 0.07 %, Mn3O4
— 0.28 %, SO3 — 0.8 %), moisture capacity — 2 %, obtained at high-temperature (600-800°С) influence on the rice husks in a vortex flow of hot oxidizing gas. It has high thermal insulation properties, high melting point, low bulk density and high porosity. It is used in the steel industry to slow down the cooling of metal by insulating its surface. The coating absorbs non-metallic inclusions (aluminum oxides) in the liquid steel.
Return the decontaminated soil into the economic turnover or the environment by improving its biological properties by introducing biogenic elements. Biogenic elements are applied in the form of agrochemicals — nitrogen-containing mineral fertilizers (ammonium nitrate, potassium nitrate, urea, phosphate fertilizers, potash) fertilizers included in the state catalog of pesticides and agrochemicals approved for use in the Russian Federation.
The heat or materials resulting from these technologies can be used for various purposes or not used if it is not profitable for economic or organizational reasons.
It is possible to get material SMR (ash, decontaminated soil) product quality certificate (voluntary certification).
CN FEA Code 2621100000. Ash and residue from the burning of municipal waste.